Believe it or not, we’re all familiar with emulsions. Have you ever added food oil to a pot of water while cooking? That’s an emulsion. Do you put dressing on your salad? It should be called salad emulsion – although, that may not have the same edible appeal. Do you drink milk? Emulsion. What about milk? Butter? Eggs? All emulsions.
If we’re referring to emulsions in the laboratory, the examples are different, but the chemistry involved is very similar – as are the mechanisms for breaking them. Continue reading Tackling Emulsions Just Got Easier
Liquid-liquid extraction (LLE), supported liquid extraction (SLE), and solid-phase extraction (SPE) have existed for decades and if you’re doing organic sample preparation, you’re probably quite familiar with at least one of these techniques. But are you familiar with all of them? How are they similar? How are they different? Let’s review! Continue reading SLE, SPE and LLE – How are Those Different?
In a never-ending list of chemical pollutants, a compound that is gaining a lot of attention is 1,4-dioxane. In fact, New Jersey just became the first state to set regulations on the quantity of 1,4-dioxane that can be present in drinking water.
1,4-dioxane, commonly called dioxane (the other two isomers – 1,2-dioxane and 1,3-dioxane are rarely ever seen), is an ether with the molecular formula of C4H8O2. Dioxane was previously used as a polar aprotic solvent. For those who remember their organic chemistry from college, SN2 reactions involve the use of polar aprotic solvents. Since its original use in laboratories, dioxane has been determined to be carcinogenic and, unlike many organic pollutants, it is completely soluble in water. Dioxane’s use as a solvent for industrial purposes has been mostly replaced with tetrahydrofuran, which has a higher boiling point and a lower toxicity. However, the story does not end there!